Synthesis and Characterization of a Bifunctional Initiator Containing Azo Bond and Aromatic Amine Group 含有偶氮键和芳香胺基双官能团引发剂的合成及表征游离基-阴离子引发剂
The results show that thermal decomposition series of bifunctional initiator is 1, thermal decomposition factor of it is 6.63 × 1010, thermal decomposition activation energy of it is 82.6KJ/ mol; 初步研究结果为,双官能度引发剂热分解级数为1级,热分解频率因子为6.63×10~(10),热分解活化能为82.6KJ/mol;
Atom Transfer Radical Polymerization of Methyl Methacrylate Using Bifunctional Initiator, 4-( Chloromethyl) Phenyltrimethoxysilane 4-(氯甲基)苯基三甲氧基硅烷引发的甲基丙烯酸甲酯的原子转移自由基聚合
Through homopolymerization posthydrolysis process, the partially hydrolyzed polyacrylamide ( PAM) with super-high relative molecular weight is synthesized by two-stage polymerization method and bifunctional initiator initiates the polymerization, and the effects of polymerization and hydrolysis technical parameters on the relative molecular mass are studied. 选择均聚后水解工艺,采用双官能度引发剂和二段聚合法合成了部分水解超高相对分子质量聚丙烯酰胺;考察了聚合工艺参数和水解条件对聚丙烯酰胺相对分子质量的影响。
Study on the Polymerization of Acrylamide Initiated by Bifunctional Initiator 双官能度引发剂引发丙烯酰胺聚合研究